Quantum Materials

Ordinary metals contain electron liquids within well-defined ‘Fermi’ surfaces at which the electrons behave as if they were non-interacting. In the absence of transitions to entirely new phases such as insulators or superconductors, interactions between electrons induce scattering that is quadratic in the deviation of the binding energy from the Fermi level. A long-standing puzzle is that certain materials do not fit this ‘Fermi liquid’ description. A common feature is strong interactions between electrons relative to their kinetic energies. One route to this regime is special lattices to reduce the electron kinetic energies. Twisted bilayer graphene is an example, and trihexagonal tiling lattices (triangular ‘kagome’), with all corner sites removed on a 2 × 2 superlattice, can also host narrow electron bands for which interaction effects would be enhanced. Here we describe spectroscopy revealing non-Fermi-liquid behaviour for the ferromagnetic kagome metal Fe₃Sn₂. We discover three C₃-symmetric electron pockets at the Brillouin zone centre, two of which are expected from density functional theory. The third and most sharply defined band emerges at low temperatures and binding energies by means of fractionalization of one of the other two, most likely on the account of enhanced electron–electron interactions owing to a flat band predicted to lie just above the Fermi level. Our discovery opens the topic of how such many-body physics involving flat bands could differ depending on whether they arise from lattice geometry or from strongly localized atomic orbitals.

Read more at Nature:
https://www.nature.com/articles/s41586-024-07085-w

Charge density wave (CDW) orders in vanadium-based kagome metals have recently received tremendous attention, yet their origin remains a topic of debate. The discovery of ScV₆Sn₆, a bilayer kagome metal featuring an intriguing $\sqrt{3}\times <!--\; \times \; -->\sqrt{3}\times <!--\; \times \; -->3$  CDW order, offers a novel platform to explore the underlying mechanism behind the unconventional CDW. Here, we combine high-resolution angle-resolved photoemission spectroscopy, Raman scattering and density functional theory to investigate the electronic structure and phonon modes of ScV₆Sn₆. We identify topologically nontrivial surface states and multiple van Hove singularities (VHSs) in the vicinity of the Fermi level, with one VHS aligning with the in-plane component of the CDW vector near the $\stackrel{¯<!--\; ¯\; -->}{K}$ point. Additionally, Raman measurements indicate a strong electron-phonon coupling, as evidenced by a two-phonon mode and new emergent modes. Our findings highlight the fundamental role of lattice degrees of freedom in promoting the CDW in ScV₆Sn₆.

Read more at Nature Communications:
https://www.nature.com/articles/s41467-024-45859-y

Electronic nematicity that spontaneously breaks rotational symmetry is a generic phenomenon in correlated quantum systems including high-temperature superconductors and the AV₃Sb₅ (A can be K, Rb or Cs) family of kagome superconductors. However, the underlying mechanism of nematicity in these systems is hard to identify because of its entanglement with other ordered phases. Recently, a family of titanium-based kagome superconductors ATi₃Bi₅ have been synthesized, where electronic nematicity occurs in the absence of charge order. It provides a platform to study nematicity in its pure form, as well as its interplay with orbital degrees of freedom. Here we reveal the band topology and orbital characters of the multiorbital RbTi₃Bi₅. We use polarization-dependent angle-resolved photoemission spectroscopy with density functional theory to identify the coexistence of flat bands, type-II Dirac nodal lines and non-trivial topology in this compound. Our study demonstrates the change in orbital character along the Fermi surface contributed by the kagome bands, implying a strong intrinsic interorbital coupling in the Ti-based kagome metals. Furthermore, doping-dependent measurements uncover the orbital-selective features in the kagome bands, which can be explained by d–p hybridization. Hence, interorbital coupling together with d–p hybridization is probably the origin of electronic nematicity in ATi₃Bi₅.

Read more at Nature Physics:
https://www.nature.com/articles/s41567-023-02215-z

Materials tuned to a quantum critical point display universal scaling properties as a function of temperature T and frequency ω. A long-standing puzzle regarding cuprate superconductors has been the observed power-law dependence of optical conductivity with an exponent smaller than one, in contrast to T-linear dependence of the resistivity and ω-linear dependence of the optical scattering rate. In this paper, we present and analyze resistivity and optical conductivity of La₂−_xSr_xCuO₄ with x = 0.24. We demonstrate ℏω/k_BT scaling of the optical data over a wide range of frequency and temperature, T-linear resistivity, and optical effective mass proportional to ∼ ln𝑇 corroborating previous specific heat experiments. We show that a T, ω-linear scaling Ansatz for the inelastic scattering rate leads to a unified theoretical description of the experimental data, including the power-law of the optical conductivity. This theoretical framework provides new opportunities for describing the unique properties of quantum critical matter.

Read more at Nature Communications:
https://www.nature.com/articles/s41467-023-38762-5

Nickel-based superconductors provide a long-awaited experimental platform to explore possible cuprate-like superconductivity. Despite similar crystal structure and d electron filling, however, superconductivity in nickelates has thus far only been stabilized in thin-film geometry, raising questions about the polar interface between substrate and thin film. Here we conduct a detailed experimental and theoretical study of the prototypical interface between Nd1−xSrxNiO2 and SrTiO3. Atomic-resolution electron energy loss spectroscopy in the scanning transmission electron microscope reveals the formation of a single intermediate Nd(Ti,Ni)O3 layer. Density functional theory calculations with a Hubbard U term show how the observed structure alleviates the polar discontinuity. We explore the effects of oxygen occupancy, hole doping and cation structure to disentangle the contributions of each for reducing interface charge density. Resolving the non-trivial interface structure will be instructive for future synthesis of nickelate films on other substrates and in vertical heterostructures.

Read more at Nature Materials:
https://doi.org/10.1038/s41563-023-01510-7

The crystalline symmetry is a defining factor of the electronic band topology in solids, where many-body interactions often induce a spontaneous breaking of symmetry. Superconductors lacking an inversion center are among the best systems to study such effects or even to achieve topological superconductivity and realize Majorana zero modes. Here, we demonstrate that TRuSi materials (with T a transition metal) belong to this class. Their bulk normal states behave as three-dimensional Kramers nodal-line semimetals, characterized by large antisymmetric spin-orbit couplings and by hourglass-like dispersions protected by glide reflection. Our muon-spin spectroscopy measurements show that certain TRuSi compounds spontaneously break the time-reversal symmetry at TRuSi while unexpectedly showing a fully gapped superconductivity. Their unconventional behavior is consistent with a unitary (s + ip) pairing, reflecting a mixture of spin singlets and spin triplets. Hence, by combining an intrinsic time-reversal symmetry-breaking superconductivity with nontrivial electronic bands, TRuSi compounds provide an ideal platform for investigating the rich interplay between unconventional superconductivity and the exotic properties of Kramers nodal-line/hourglass fermions.

Read more at Science Advances:
https://www.science.org/doi/10.1126/sciadv.abq6589